One of two requests from biggestloser1000, here are each of the unlockable characters in Powerpuff Z 3 and the methods in which you unlock them:\r
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Brick: Defeat Brick in Story Mode.\r
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Boomer: Defeat Boomer in Story Mode.\r
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Butch: Defeat Butch in Story Mode.\r
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Infinite Destinies Dark Powerpuff Girls: Complete Story Mode with Blossom, Bubbles, and Buttercup.\r
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Blitzy: Complete Tournament Mode in less than 8 minutes, then fight and defeat Blitzy.\r
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DigitalX: Get a score of 10 KOs in Skirmish Mode, then fight and defeat DigitalX.\r
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Bane: Get a Perfect against Bleak in Story Mode, then fight and defeat Bane.